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(6)Prevention of crashes. Public Citizen hopes that the mandatory installation of EDRs in the commercial vehicle fleet will yield crash reductions comparable to the decreases observed in the European studies. We anticipate that, as in the studies, the biggest safety gains from influences upon driver behavior would similarly occur in the commercial trucking fleet. As some of the comments in this docket clearly indicate, the commercial trucking industry is troubled by the ability of EDRs to corroborate the figures recorded in hours of service log books. Judging by the trucking industry s intense opposition to the mandatory installation of EDRs in commercial trucks, Public Citizen suspects that the presence of EDRs in commercial vehicles could substantially improve both industry practices and commercial driver behavior, particularly as to the rampant problem of drivers who continue driving while fatigued.

early on the reaction coordinate, artha over para substitution is favored Weak electrophiles or weakly basic aromatics, in turn, tend to proceed through transition states lying late on the reaction coordinate Weaker alkylating agents result in increasing selectivity of the formation of the para isomer (assuming that kinetic conditions are maintained) When good correlations are found between rates and G-complex stabilities of arenes, Brown's one-step mechanism with rate-determining G-complex formation determines both substrate and positional selectivities and Brown's selectivity relationship is valid Care must be exercised, however, to ascertain that kinetic conditions are always maintained If such correlation does not hold, Olah's two-step mechanism with separate rc- and G-complex formation may be operative The nature of the initial "first complex" is still argued.

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In some instances, encounter complexes or charge transfer complexes are suggested to be involved but there is increasing agreement about the necessity of two separate steps to explain low substrate but high positional selectivities Of course, it must be emphasized again, that if isomerizing conditions prevail no kinetic treatment of selectivities is possible Studies by Nakane et al also support the two-step mechanism when alkylation is carried out with alkyl halides under substantially nonionizing conditions 128 ,129 It was further shown that in nonpolar organic solvents carbocations rather than the polarized complexes participate directly in the formation of the first rc complex BF3-H20 catalyzes ethylation,130 isopropylation,131 and benzylation 132 through the corresponding carbocations Accordingly, ethylbenzene equally labeled in both r:x and ~ positions was obtained when [2-14q-ethyl halides were reacted in hexane solution in the presence of boron trifluoride, 130 BF3-H20,133 or aluminum bromide.

134 The benzyl cation was, however, shown to be involved in TiCI 4- and SbCIs-catalyzed benzylation in polar solvents 13S The stereochemical outcome of Friedel-Crafts alkylation may be either inversion (nucleophilic displacement) or racemization (involvement of a trivalent flat carbocation) Most transformations were shown to occur with complete racemization In a few instances, inversion or retention was observed For example, the formation of (-)-1,2-diphenylpropane [(-)-28] from (-)-26 was interpreted to take place through the 27 nonsymmetrically rc-bridged carbocation, ensuring 50-100% retention of configuration: 136.

FIGURE 2.6 InDesign s Tools panel has 32 tools available (at left), many via pop-out menus (shown at center). You can see a tool s name by hovering the mouse over it to get a Tool Tip (at right).

Dreamweaver is extremely extensible custom functions are better handled, server-side markup is more acceptable, and more third-party tags are supported. Many of these features depend on hidden capabilities that are not noticeable in the final HTML page. The Web designer, however, must take them into account. Dreamweaver employs user-selectable highlighting to mark areas on a Web page under construction. The Highlighting panel of the Preferences dialog box, shown in Figure 4-5, enables you to choose the highlight color for eight different types of extended objects: Mouse-Over Editable Regions Nested Editable regions Locked Regions Library Items Third-Party Tags Untranslated Live Data Translated Live Data

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Many text editors, like vim (shown here), offer syntax highlighting, automatic code indentation, and more.

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Table 20-4 Characterization of Mixers Used in Pulping Applications Suspension Residence Concentration, Time (s) Cm 180 180 10 10 30 240 40 200 Power Dissipation (MW/m3 ) 0.02 0.05 0.45 1.1 1.8 0.08 0.12 0.16 Energy Expenditure (MJ/t) 120 90 63 160 180 11 86 50 20

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